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Tuesday, 27 February 2007
SAT Question of the Day
Which of the following molecule has the second largest dipole moment?
The correct answer is NH3. The largest dipole moment belongs to HF, obviously. NH4+ and BF3 have a dipole moment equal with 0. (Draw the geometry of each and you will see) Between NH3 and NF3, NH3 has a greater dipole moment because the unshared electron pair acts in the same direction as the dipole moment, while for the NF3 it acts in different directions, and thus the total effect is minimised.
The dipole moment of NF3 is 0.23D and the dipole moment of NH3 is 1.85D. This are the literature values and of course they are real. I am sorry for what your teacher said, maybe for her lecture you have to go that way. The N-F is more polar than the N-H bond, this is true but the dipole moment of the molecule is much less. In other words the bond dipoles go opposite directions on NH3 and NF3 For NH3, the net dipole is enhanced by the lone pair while for NF3, the net dipole is decreased due to the lone pair. Hope this helps.
After you add up the vectors, you will have to take into account also the effect of the unshared pair of electrons.
i dont get how the bond dipoles go in opposite directions. how are you supposed to know that the net dipole of NH3 is enhanced by the lone pair and the net dipole of NF3 is decreased by it ??
The dipole moment is represented as a vector that points from the least electronegative element to the most electronegative one.This means that the electrons that form the sigma bond are somehow "migrating" towards the most electronegative element. So the density charge on the most electronegative element is larger than the density on the other atom. For NH3 the dipole moments point from H to N and when you add up all three vectors corresponding to the 3 bonds you will obtain a vector that points from somewhere on the left of the nitrogen atom towards it, while for the NF3, fluorine is the most electronegative element and therefore the dipole moment will point from the N atom to the F:
H -->N: , F <-- N:
That arrow represents the cumulate dipole moment and it means that a partially positive charged is situated on the H atoms and a negative one on the Nitrogen (This is the meaning of the dipole moment, it point from the positive end to the negative one )Therefore the pair of lone electrons(which are obviously negative charged) will enhance the partially negative charge on the N atom, and therefore enhancing the total dipole moment (By making the charge difference larger, the dipole moment is increased). For the NF3, F is more electronegative and it has a partially negative charge while N has a partially positive charge (see the arrow representing the dipole moment). Therefore the pair of electron(which are negatively charged) will reduce the positive charge on the N atom (you add them up algebraically). So the charge difference is less and the dipole moment is less.
sorry to post here so late, but I have just discovered this site (by the way, it is a great one). I don't understand why does the NH4 ion have the dipole moment 0 if it is a ion. I agree that the geometry is the same as CH4 and would indicate 0 dipole moment if it would have no charge, but how can a charged ion have 0 dipole moment? I am a little confused
NH4+ has no permanent dipole, the charge isn't associated with any particular hydrogen....anything with electrons and protons can have an instaneous dipole...even a single atom
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370 comments:
1 – 200 of 370 Newer› Newest»is it BF3?
or is it NF3
Its BF3...i think:D
The correct answer is NH3.
The largest dipole moment belongs to HF, obviously.
NH4+ and BF3 have a dipole moment equal with 0. (Draw the geometry of each and you will see)
Between NH3 and NF3, NH3 has a greater dipole moment because the unshared electron pair acts in the same direction as the dipole moment, while for the NF3 it acts in different directions, and thus the total effect is minimised.
my ap chem teacher said it would be NF3 ...
The dipole moment of NF3 is 0.23D and the dipole moment of NH3 is 1.85D.
This are the literature values and of course they are real.
I am sorry for what your teacher said, maybe for her lecture you have to go that way.
The N-F is more polar than the N-H bond, this is true but the dipole moment of the molecule is much less.
In other words the bond dipoles go opposite directions on NH3 and NF3
For NH3, the net dipole is enhanced by the lone pair while for NF3, the net dipole is decreased due to the lone pair.
Hope this helps.
After you add up the vectors, you will have to take into account also the effect of the unshared pair of electrons.
i dont get how the bond dipoles go in opposite directions. how are you supposed to know that the net dipole of NH3 is enhanced by the lone pair and the net dipole of NF3 is decreased by it ??
The dipole moment is represented as a vector that points from the least electronegative element to the most electronegative one.This means that the electrons that form the sigma bond are somehow "migrating" towards the most electronegative element. So the density charge on the most electronegative element is larger than the density on the other atom.
For NH3 the dipole moments point from H to N and when you add up all three vectors corresponding to the 3 bonds you will obtain a vector that points from somewhere on the left of the nitrogen atom towards it, while for the NF3, fluorine is the most electronegative element and therefore the dipole moment will point from the N atom to the F:
H -->N: , F <-- N:
That arrow represents the cumulate dipole moment and it means that a partially positive charged is situated on the H atoms and a negative one on the Nitrogen (This is the meaning of the dipole moment, it point from the positive end to the negative one )Therefore the pair of lone electrons(which are obviously negative charged) will enhance the partially negative charge on the N atom, and therefore enhancing the total dipole moment (By making the charge difference larger, the dipole moment is increased).
For the NF3, F is more electronegative and it has a partially negative charge while N has a partially positive charge (see the arrow representing the dipole moment).
Therefore the pair of electron(which are negatively charged) will reduce the positive charge on the N atom (you add them up algebraically). So the charge difference is less and the dipole moment is less.
ohhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhh that helped soooooooooooo much !!! thxxxxxxx
sorry to post here so late, but I have just discovered this site (by the way, it is a great one). I don't understand why does the NH4 ion have the dipole moment 0 if it is a ion. I agree that the geometry is the same as CH4 and would indicate 0 dipole moment if it would have no charge, but how can a charged ion have 0 dipole moment? I am a little confused
NH4+ has no permanent dipole, the charge isn't associated with any particular hydrogen....anything with electrons and protons can have an instaneous dipole...even a single atom
you explained this realllllllllllly well, you should write a book
I always motivated by you, your opinion and way of thinking, again, appreciate for this nice post.
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